Humboldt-Universität zu Berlin - Mathematisch-Naturwissenschaftliche Fakultät - Stereoselektive CC-Knüpfung

Publications

Voigt, B.; Mahrwald, R.

Domino and Rearrangement Reaction in Carbohydrate Chemistry

John Wiley and Sons, 2015

Editors: Zbigniew J. Witczak, Roman Bielski

Organocatalyzed Cascade Reaction in Carbohydrate Chemistry

 

Witte, S. N. R.; Voigt, B.; Mahrwald, R.

Synthesis 2015; 47, 2249–2255.

Amine-​Catalyzed Cascade Reactions of Unprotected and Un-​activated Carbohydrates: Direct Access to C-​Glycosides

 

Richter, C.; Voigt, B.; Mahrwald, R.

RSC Advances 20155, 45571–45574.

Amine-​catalyzed cascade reactions of ketoses with 1,​3-​dicarbonyl compounds

 

Voigt, B.; Linke, M.; Mahrwald, R.

Organic Letters 201517, 2606–2609.

Multicomponent Cascade Reactions of Unprotected Carbohydrates and Amino Acids

 

Heidlindemann, M.; Hammel, M.; Scheffler, U.; Mahrwald, R.; Hummel, W.; Berkessel, A.; Groeger, H.

Journal of Organic Chemistry 201580, 3387–339.

Chemoenzymatic Synthesis of Vitamin B5-​Intermediate (R)​-​Pantolactone via Combined Asymmetric Organo- and Biocatalysis

highlighted by

ACS Select virtual issue http://pubs.acs.org/page/vi/organocatalysis

 

Matviitsuk, A.; Berndt, F.; Mahrwald, R.

Organic Letters 201416, 5474–5477.

Four into One: Organo-​catalyzed Stereoselective Conjugate Addition of Unprotected and Un-​activated Carbohydrates

 

Scheffler, U.; Mahrwald, R.

Journal of Visualized Experiments 2014, 86, e51258/1–e51258/6.

Retropinacol​/cross-​pinacol coupling reactions - a catalytic access to 1,​2-​unsymmetrical diols

 

Voigt, B.; Mahrwald, R.

Chemical Communications 2014, 50, 817-819.

Organocatalyzed cascade reactions of carbohydrates - a direct access to C-glycosides

 

Mahrwald, R.

Comprehensive Enantioselective Organocatalysis

WILEY, 2013, 69-95.

Editor: Peter I. Dalko

Chiral Imidazolidinone (MacMillan's) Catalyst

 

Schmalisch, S.; Mahrwald, R.

Organic Letters 201315, 5854-5857.

Organo-catalyzed Direct Glycosylation of Unprotected and Unactivated Carbohydrates

 

Scheffler, U.; Mahrwald, R.

Chemistry - A European Journal 201319, 14346-14396.

Recent Advances in Organocatalytic Methods for Asymmetric C-C Bond Formation

 

Voigt, B.; Matviitsuk, A.; Mahrwald, R.

Tetrahedron, 2013, 69(21), 4302-4310.

Organocatalyzed Knoevenagel-addition - simple access to carbon chain-elongated branched carbohydrates

 

Mahrwald R.

Drug Discovery Today. Technologies 201310, e29-36.

Organocatalytic methods for C-C bond formation

 

Böhm, M.; Proksch, K.; Mahrwald, R.

European Journal of Organic Chemistry, 2013, 6, 1046–1049.

Decarboxylative Mannich Reactions

 

Weinberger, M.; Berndt, F.; Mahrwald, R.; Ernsting, N. P.; Wagenknecht, H.-A.

Journal of Organic Chemistry 201378, 2589-2599.

Synthesis of 4-Aminophthalimide and 2,4-Diaminopyrimidine C-Nucleosides as Isosteric Fluorescent DNA Base Substitutes

 

Scheffler, U.; Mahrwald, R.

Helvetica Chimica Acta, 2012, 95(10), 1970-1975.

A one-pot cross-pinacol coupling/rearrangement procedure

 

Scheffler, U.; Stoesser, R.; Mahrwald, R.

Advanced Synthesis & Catalysis 2012, 354(14-15), 2648-2652, S2648/1-S2648/61

Retropinacol/Cross-Pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

 

Weigel, A.; Pfaffe, M.; Sajadi, M.; Mahrwald, R.; Improta, R.; Barone, V.; Polli, D.; Cerullo, G.; Ernsting, N. P.; Santoro, F.

Physical Chemistry Chemical Physics 2012, 14(38), 13350-13364.

Barrierless photoisomerisation of the "simplest cyanine": Joining computational and femtosecond optical spectroscopies to trace the full reaction path

 

Berndt, F.; Dobryakov, A. L.; Quick, M.; Mahrwald, R.; Ernsting, N. P.; Lenoir, D.; Kovalenko, S. A.

Chemical Physics Letters 2012, 544, 39-42.

Long-lived perpendicular conformation in the photoisomerization path of 1,1'-dimethylstilbene and 1,1'-diethylstilbene

 

Voigt, B.; Scheffler, U.; Mahrwald, R.

Chemical Communications 2012, 48(43), 5304-5306.

Stereoselective amine-catalyzed carbohydrate chain elongation

 

Rohr, K.; Mahrwald, R.

Organic Letters 2012, 14(8), 2180-2183.

Isoleucine-catalyzed direct asymmetric aldol addition of enolizable aldehydes

 

Lam, Yu-hong; Houk, K. N.; Scheffler, Ulf; Mahrwald, Rainer

Journal of the American Chemical Society 2012, 134(14), 6286-6295.

Stereoselectivities of Histidine-Catalyzed Asymmetric Aldol Additions and Contrasts with Proline Catalysis: A Quantum Mechanical Analysis

 

Scheffler, U.; Mahrwald, R.

Journal of Organic Chemistry 2012, 77(5), 2310-2330.

Histidine-Catalyzed Asymmetric Aldol Addition of Enolizable Aldehydes: Insights into its Mechanism

 

Pfaffe, M.; Mahrwald, R.

Organic Letters 2012, 14(3), 792-795.

Direct Glycosylation of Un-protected and Un-activated Carbohydrates under Mild Conditions

 

Seifert, A; Rohr, K.; Mahrwald, R.
Tetrahedron, 2012, 68(4), 1137-1144
Acid-catalyzed aldol-Merrwein-Ponndorf-Verley-etherification reactions - access to defined configured quaternary stereogenic centers 

 

Mahrwald, R.

Comprehensive Chirality. Elsevier 20122, 370-397.

Editors: Carreira, Erick M. and Yamamoto, Hisashi

Selected diastereoselective reactions: aldoltype additions

 

Berndt, F.; Ioffe, I.; Granovsky, A. A.; Mahrwald, R.; Tannert, S.; Kovalenko, S. A.; Ernsting, N. P.

Journal of Photochemistry and Photobiology, A: Chemistry 2012234, 164-170.

7-Amino-dibenzofuran-3-carboxylate: A new probe for femtosecond dynamic microsolvation studies of biomolecules

 

Scheffler, U.; Mahrwald, R.

Synlett 2011, (12), 1660-1667.

Asymmetric organocatalyzed direct aldol additions of enolizable aldehydes

 

Berndt, F.; Sajadi, M.; Ernsting, N. P.; Mahrwald, R.

Carbohydrate Research 2011346, 2960-2964.

Covalent linkage of N-methyl-6-oxyquinolinium betaine to trehalose

 

Biemann, L.; Kovalenko, S. A.; Kleinermanns, K.; Mahrwald, R.; Markert, M.; Improta, R.

Journal of the American Chemical Society 2011133, 19664-19667.

Excited State Proton Transfer Is Not Involved in the Ultrafast Deactivation of Guanine-Cytosine Pair in Solution

 

Rohr, K.; Mahrwald, R.
Org. Lett., 2011, 13(7), 1878-1880
Stereoselective Direct Amine-Catalyzed Decarboxylative Aldol Addition 

 

Seifert, A.; Scheffler, U.; Markert, M.; Mahrwald, R.
Organic Letters, 2010, 12(8), 1660-1663
Asymmetric Acid-Catalyzed Meerwein-Ponndorf-Verley-Aldol Reactions of Enolizable Aldehydes

Markert, M.; Scheffler, U.; Mahrwald, R.
J. Am. Chem. Soc., 2009, 131, 16642-16643
Asymmetric Histidine-Catalyzed Cross-Aldol Reactions of Enolizable Aldehydes: Access to defined Configured Quaternary Stereogenic Centers  

highlighted by
Synform 2010, A16
Synfacts 2010, 101
see also JACS Image Challenge 98

Seifert, A.; Mahrwald, R.
Tetrahedron Lett., 2009, 50, 6466-6468
Stereoselective one-pot synthesis of highly differtly substituted thiochromans 

Rohr, K.; Herre, R.; Mahrwald, R.
J. Org. Chem., 2009, 74 (7), 3744-3749
Towards Asymmetric Aldol-Tishchenko Reactions with Enolizable Aldehydes - Access to Defined Configured Stereotriads, Tetrads and Stereopentads

Rohr, K.; Mahrwald, R.
Bioorg. Med. Chem. Let., 2009, 19, 3949
Catalyst-free tandem aldol condensation / Michael addition of 1,3-cyclohexanediones with enolizable aldehydes