Transition Metal Chemistry and Coordination Chemistry
Nomenclature of coordination compounds.
Complex formation – equilibria – complex stability – chelate
effect.
Types and classification of ligands.
Oxidation state formalism.
Transition metal series – d electron configuration.
Coordination numbers – coordination polyhedra.
Isomerism in coordination compounds.
Systematic nomenklature of stereoisomeric coordination compounds
(polyhedron symbol, configuration index, chirality symbol).
Molecular symmetry (symmetry elements – symmetry operations –
multiplication of symmetry operations).
Group theory (axioms - symmetry point groups - multiplication tables -
characters and character tables – irreducible and reducible
representations).
Introduction to MO theory (Symmetry adapted linear combination of
atomic orbitals – Symmetry adapted molecular orbitals – construction of
MO schemes – MO-schemes of H2, BH3 NH3
and CH4).
Chemical bonding of d-block elements.
σ bonds – π bonds – δ bonds – classification of complexes (n-complexes
– π-complexes and – σ-complexes – MO schemes of octahedral complexes –
orbital splitting diagram – low-spin and high-spin complexes – spin
equilibria – spektrochemical series – 18 valence electron rule –
σ-donor ligands – π-donor ligands – π-acceptor ligands).
Bonding in transition metal complexes (MO-scheme of octahedral
complexes with π-donor Ligands – MO-Scheme of octahedral complexes with
π-acceptor ligands – Metal-ligand back bonding – MO-scheme of
square-planar complexes and trigonal-bipyramidal complexes)
A. F. Holleman, . Wiberg: "Lehrbuch der
Anorganischen Chemie", Walter de Gruyter Verlag, ISBN 3-11-012641-9,
(1995).
D. F. Shriver, P. W. Atkins, C. H. Langford: "Inorganic Chemistry",
Oxford University Press, ISBN 0-19-855396-X, (1994).
J. Yves: "An introduction to molecular orbitals", Oxford University
Press, ISBN 0-19-506918-8, (1993).
E. Riedel: "Moderne Anorganische Chemie", Walter de Gruyter Verlag,
ISBN 3-11-015672-5, (1999).