Humboldt-Universität zu Berlin - Faculty of Mathematics and Natural Sciences - Ray Group

 

M. Sc. Dustin Kass

Tel: +49 30 2093-82802

dustin.kass@hu-berlin.de

Room: 1'204

ORCID: https://orcid.org/0000-0003-2832-2127

Research topic

Synergetic effects during activation of small molecules.

Publications

1. "A bis-Phenolate Carbene-Supported bis-µ-Oxo Iron(IV/IV) Complex with a [Fe^IV(µ-O)₂Fe^IV] Diamond Core Derived from Dioxygen Activation"
   L. Gravogl, D. Kass, O. Pyschny, F. W. Heinemann, M. Haumann, S. Katz, P. Hildebrandt, H. Dau, A. Swain, R. García-Serres K. Ray, D. Munz, K. Meyer, J. Am. Chem. Soc. 2024.
   DOI: 10.1021/jacs.4c07582 
2. "A Bioinspired Nonheme Fe^III-(O₂^2-)-Cu^II Complex with an S_t = 1 Ground State"
   D. Kass, S. Katz, H. Özgen, S. Mebs, M. Haumann, R. García-Serres, H. Dau, P. Hildebrandt, T. Lohmiller, K. Ray, J. Am. Chem. Soc. 2024.
   DOI: 10.1021/jacs.4c04492
3. "Origin of Unprecedented Formation and Reactivity of Fe^IV=O Species viaOxygen Activation: Role of Noncovalent Interactions and Magnetic Coupling"
   A. Sen, N. J. Britto, D. Kass, K. Ray, G. Rajaraman, Inorg. Chem. 2024.
   DOI: 10.1021/acs.inorgchem.4c00371
4. "Trapping of a phenoxyl radical at a non-haem high-spin iron(II) centre"
   D. Kass, V. Larson, T. Corona, U. Kuhlmann, P. Hildebrandt, T. Lohmiller, E. Bill, N. Lehnert, K. Ray, Nat. Chem. 2024.
   DOI: 10.1038/s41557-023-01405-9
5. "Two Allogons of an O2-activating Bis(disiloxido)ferrate(II) Accessible Selectively just by Variation of the Crystallization Temperature"
   F. Beckmann, P. Woite, S. Yelin, D. Kass, D. Usvyat, M. Römelt, C. Limberg, Chem. - Eur. J. 2023, e202303614.
   DOI: 10.1002/chem.202303614
6. "Reactivities of iron(IV)-oxido compounds with pentadentate bispidine ligands"
   K. Bleher, P. Comba, D. Kass, K. Ray, H. Wadepohl, J. Inorg. Biochem. 2023, 112123.
   DOI: 10.1016/j.jinorgbio.2023.112123
7. "Spectroscopic Properties of a Biologically Relevant [Fe₂(µ-O)₂] Diamond Core Motif with a Short Iron-Iron Distance"
   D. Kass, S. Yao, K. Krause, T. Corona, L. Richter, T. Braun, S. Mebs, M. Haumann, H. Dau, T. Lohmiller, C. Limberg, M. Drieß, K. Ray, Angew. Chem. Int. Ed. 2022, 62, e202209437.
   DOI: 10.1002/anie.202209437
8. "Spektroskopische Eigenschaften eines biologisch-relevanten [Fe₂(μ-O)₂] Diamond-Core-Motivs mit einem kurzen Eisen-Eisen-Abstand"
   D. Kass, S. Yao, K. Krause, T. Corona, L. Richter, T. Braun, S. Mebs, M. Haumann, H. Dau, T. Lohmiller, C. Limberg, M. Drieß, K. Ray, Angew. Chem. Int. Ed. 2022, 135, e202209437. 
   DOI: 10.1002/ange.202209437

9. "Modelling the coordination environment in α-ketoglutarate dependent oxygenases - a comparative study on the effect of N- vs. O-ligation"
   K. Warm, D. Kass, M. Haumann, H. Dau, K. Ray, Z. Allg. Anorg. Chem. 2022, 648, e202100310.
   DOI: 10.1002/zaac.202100310

10. "Direct growth of crystalline triazine-based graphdiyne using surface-assisted deprotection–polymerisation"
    R. Kulkarni, J. Huang, M. Trunk, D. Burmeister, P. Amsalem, J. Müller, A. Martin, N. Koch, D. Kass, M. J. Bojdys, Chem. Sci. 2021, 12, 12661-12666.
    DOI: 10.1039/D1SC03390E

11. "High-spin square planar iron(II) alkali metal siloxide complexes – influence of the alkali metal and reactivity towards O₂ and NO"
    F. Beckmann, D. Kass, M. Keck, S. Yelin, S. Hoof, B. Cula, C. Herwig, K. B. Krause, D. Ar, C. Limberg, Z. Allg. Anorg. Chem. 2021, 647, 960-967.
    DOI: 10.1002/zaac.202100059

12. "Stoichiometric Formation of an Oxoiron(IV) Complex by a Soluble Methane Monooxygenase Type Activation of O₂ at an Iron(II)-Cyclam Center"
    D. Kass, T. Corona, K. Warm, B. Braun-Cula, U. Kuhlmann, E. Bill, S. Mebs, M. Swart, H. Dau, M. Haumann, P. Hildebrandt, K. Ray, J. Am. Chem. Soc. 2020, 142, 5924-5928.
    DOI: 10.1021/jacs.9b13756

Conferences

1. 18. Koordinationschemie-Treffen 2024 (honored with presentation award)
2. 4th Small Molecule Activation Conference (awarded with "Best Short talk")
3. 15. Koordinationschemie-Treffen 2019 (honored with presentation award)