Humboldt-Universität zu Berlin - Faculty of Mathematics and Natural Sciences - Ray Group

Tarali Devi

 
Dr. rer. nat. Tarali Devi

 

ORCID: https://orcid.org/0000-0002-3460-328

 

Previous research topic

Biomimetic modelling and spectroscopic studies of non-heme enzyme active sites.

 

Publications
  1. "Reinvestigation of the mechanism of dioxygen activation at a MnII(cyclam) center"
    T. Devi, S. Mebs, D. J. Barman, A. Opis-Basilio, M. Haumann, K. Ray, J. Inorg. Biochem. 2025, 264, 112809.
    DOI: 10.1016/j.jinorgbio.2024.112809
  2. "A high-spin alkylperoxo-iron(III) complex with cis-anionic ligands_ implications for the superoxide reductase mechanism"
    T. Devi, K. Dutta, J. Deutscher, S. Mebs, U. Kuhlmann, M. Haumann, B. Cula, H. Dau, P. Hildebrandt, K. Ray, Chem. Sci. 2024, 15, 528-533.
    DOI: 10.1039/D3SC05603
  3. "Acid-promoted hydride transfer from an NADH analogue to a Cr(III)-superoxo complex via a proton-coupled hydrogen atom transfer"
    T. Devi, Y.‐M. Lee, W. Nam, Dalton Trans. 2021, 50, 675-680.
    DOI: 10.1039/D0DT04004E
  4. "Metal ion-coupled electron-transfer reactions of metal-oxygen complexes"
    T. Devi, Y. M. Lee, W. Nam, S. Fukuzumi, Coord. Chem. Rev. 2020, 410, 213219.
    DOI: 10.1016/j.ccr.2020.213219
  5. "Tuning Electron-Transfer Reactivity of a Chromium(III)-superoxo Complex Enabled by Calcium Ion and Other Redox-Inactive Metal Ions" 
    T. Devi, Y.‐M. Lee, W. Nam, S. Fukuzumi, J. Am. Chem. Soc. 2020, 142, 365-372.
    DOI: 10.1021/jacs.9b11014
  6. "Aromatic hydroxylation of anthracene derivatives by a chromium(III)-superoxo complex via proton-coupled electron transfer" 
    T. Devi, Y.-M. Lee, W. Nam, S. Fukuzumi, Chem. Commun. 2019, 55, 8286-8289. 
    DOI: 10.1039/c9cc03245b
  7. "Remarkable Acid Catalysis in Proton-Coupled Electron-Transfer Reactions of a Chromium(III)-Superoxo Complex" 
    T. Devi, Y.-M. Lee, W. Nam, S. Fukuzumi, J. Am. Chem. Soc. 2018, 140, 8372-8375.
    DOI: 10.1021/jacs.8b02303
  8. "A Chromium(III)-Superoxo Complex as a Three-Electron Oxidant with a Large Tunneling Effect in Multi-Electron Oxidation of NADH Analogues" 
    T. Devi, Dr. Y.‐M. Lee, J. Jung, M. Sankaralingam, W. Nam, S. Fukuzumi, Angew. Chem. Int. Ed. 2017, 129, 3564-3569. 
    DOI: 10.1002/anie.201611709