Humboldt-Universität zu Berlin - Mathematisch-Naturwissenschaftliche Fakultät - Arbeitsgruppe Ray

Xenia Engelmann

Dr. rer. nat. Xenia Engelmann



Früheres Forschungsthema

Biomimetische Sauerstoffaktivierung an frühen Übergangsmetallen.


  1. "Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide"
    X. Engelmann, D. D. Malik, T. Corona, K. Warm, E. R. Farquhar, M. Swart, W. Nam, K. Ray, Angew. Chem. Int. Ed. 2019, 131, 4052-4056. 
    DOI: 10.1002/anie.201812758

  2. "Water Oxidation Reaction Mediated by an Octanuclear Iron-Oxo Cluster"
    J. Deutscher, T. Corona, K. Warm, X. Engelmann, S. Sobottka, B. Braun-Cula, B. Sarkar, K. Ray, Eur. J. Inorg. Chem. 2018, 45, 4925–4929.
    DOI: 10.1002/ejic.201800269

  3. "Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes"
    S. C. Chan, P. Gupta, X. Engelmann, Z. Z. Ang, R. Ganguly, E. Bill, K. Ray, S. Ye, J. England, Angew. Chemie Int. Ed., 2018, 57, 15717-15722.
    DOI: 10.1002/anie.201809158

  4. "Four-electron reduction of dioxygen to water by a trinuclear copper complex"
    X. Engelmann, E. R. Farquhar, J. England, K. Ray, Inorg. Chem. Acta, 2018, 481, 159-165.
    DOI: 10.1016/j.ica.2017.11.014

  5. "C-H activation and nucleophilic substitution in a photochemically generated high valent iron complex"
    J. H. Lim, X. Engelmann, S. Corby,  R. Ganguly, K. Ray, H. S. Soo, Chem. Sci. 2018, 9, 3992-4002.
    DOI: 10.1039/C7SC05378A

  6. "A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3O Macrocyclic Ligand" 
    I. Monte Pérez, X. Engelmann, Y.-M. Lee, M. Yoo, K. Elumalai, E. R. Farquhar, E. Bill, J. England, W. Nam, M. Swart, K. Ray, Angew. Chem. 2017, 56, 14384-14388.
    DOI: 10.1002/anie.201707872

  7. "A New Domain of Reactivity for High-Valent Dinuclear [M(µ-O2M'] Complexes in Oxidation Reactions"
    X. Engelmann, S. Yao, E. R. Farquhar, T. Szilvási, U. Kuhlmann, P. Hildebrandt, M. Driess, K. Ray, Angew. Chem. 201656, 297-301.
    DOI: 10.1002/anie.201607611

  8. "Oxidationsreaktionen mit bioinspirierten einkernigen Nicht-Häm-Oxidometallkomplexen"
    X. Engelmann, I. Monte Pérez, K. Ray, Angew. Chem. 2016, 128, 7760-7778.
    DOI: 10.1002/ange.201600507

  9. "A cobalt(II) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions"
    S. Kundu, P. Chernev, X. Engelmann, C. S. Chung, H. Dau, E. Bill, J. England, K. RayW. Nam, Dalton Trans. 201645, 14538-14543.
    DOI: 10.1039/C6DT01815G